Homologous Series


A homologous series is a family of organic compounds containing a particular characteristic group and exhibiting similar properties. For example, the compounds given below belong to the alcohol family.
CH3OH methyl alcohol (methanol)
CH3CH2CH2OH propyl alcohol (1-propanol)
CH3CH2.CH2.CH2OH butyl alcohol (1-butanol)

Characteristics of a Homologous Series

All members of a homologous series exhibit some common characteristics. They are:
  • All the members of a homologous series can be represented by a common general formula, as they have the same functional group. For example, alkanes can be represented by the formula CnH2n+2.
CH4 C2H6 C3H8 C4H10
Methane Ethane Propane Butane
  • Each member of a homologous series has a common difference of -CH2 from the next higher or lower member.
  • Common general methods of preparation exist for all members of the series.
  • All members exhibit similar chemical behavior.
  • An increase in molecular mass of members within a homologous series show a similar regular gradation of the physical properties, such as, physical state, melting and boiling points etc.

Source:http://www.tutorvista.com/content/chemistry/chemistry-iii/organic-chemistry/homologous-series.php